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铸膜液溶剂对醋酸酯型改性淀粉膜结构及性能的影响
Effects of solvents on the structure and properties of starch acetate membranes
【摘要】 以醋酸酯型改性淀粉(简称醋酸酯淀粉)为原料,分别以二氯甲烷、三氯甲烷、丙酮和1,4-二氧六环为铸膜液溶剂,用浇铸法制备醋酸酯淀粉膜,并研究了铸膜液溶剂对膜致密性、膜结晶度、膜耐水性及膜在土壤中降解速率的影响.实验结果表明:铸膜液溶剂的挥发速度越慢,则膜的致密性越好,结晶度越高;醋酸酯淀粉膜在土壤中能降解,致密性好的膜耐水性能较好并且土壤降解速率较低.
【Abstract】 The starch acetate membranes were cast with different solvents,namely,dichloromethane,chloroform,acetone and 1,4-dioxane.The effects of casting solvents on membrane compactness,crystallinity,water-resistance,and degradation in soil were investigated.The results have shown that the slower the volatility of solvents is,the denser the membrane and the higher the crystallinity are.Moreover,it was noted that water-resistance of membrane was better and the degradation in soil was slower for the denser membranes.
【关键词】 醋酸酯淀粉;
控制释放;
铸膜液溶剂;
膜结构;
耐水性能;
土壤降解速率;
【Key words】 starch acetate; controlled release; solvents; membrane morphology; water-resistance; degradation in soil;
【Key words】 starch acetate; controlled release; solvents; membrane morphology; water-resistance; degradation in soil;
【基金】 国家863计划"新型缓控制释放氮肥研制及产业化"(2001AA246021)
- 【文献出处】 膜科学与技术 ,Membrane Science and Technology , 编辑部邮箱 ,2005年01期
- 【分类号】TB43
- 【被引频次】7
- 【下载频次】211