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废旧电脑主板中Cu、Al的湿法浸出研究

Leaching of Copper and Aluminium from Waste Computer Boards

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【作者】 陈占华顾帼华锁军

【Author】 CHEN Zhan-hua,GU Guo-hua,SUO Jun (School of Resource Processing and Bio-engineering, Central South University, Changsha 410083, Hunan, China)

【机构】 中南大学资源加工与生物工程学院中南大学资源加工与生物工程学院 湖南长沙410083湖南长沙410083湖南长沙410083

【摘要】 首先采用电选对破碎后的电脑主板实现金属与非金属的分离,其中金属导体产率为25%,非金属产品产率为75%。然后以硫酸和双氧水为反应试剂,从电选的金属产品中浸出铜和铝,考察了浸出时间、硫酸和双氧水用量、浸出温度等工艺条件对反应的影响。试验结果表明:固液比为1∶100,浸出时间为4h,双氧水用量为0.2mol,硫酸用量为0.5mol,温度为70℃,铜的浸出率可达到100%,铝的浸出率可达到97.5%,实现了资源的再生利用。

【Abstract】 The waste computer boards were crushed to smaller than -0.85 mm by a crusher and then separated into two parts of 25% conducting and 75% non-conducting materials by an electrostatic separator. The conducting material, which contained copper and aluminium, was leached by sulphuric acid and hydrogen peroxide. The influences of leaching time, reaction temperature and the amount of sulphuric acid and hydrogen peroxide were investigated. The results indicate that the favorable conditions are the ratio of 1 to 100 of solid to liquid, the additions of 0.5 mol sulphuric acid and 0.2 mol hydrogen peroxide and the temperature of 70 ℃ and leaching time of 4 hrs. The best dissolution rates of copper and aluminium were 100% and 97.25%, respectively.

【关键词】 废旧电脑主板湿法浸出CuAl
【Key words】 waste computer boardsleachingcopperaluminium
【基金】 全国优秀博士论文专项资金资助项目(200145);湖南省杰出青年专家科技专项计划资助项目(02JJYB007)
  • 【文献出处】 矿冶工程 ,Mining and Metallurgical Engineering , 编辑部邮箱 ,2005年02期
  • 【分类号】TF111.3
  • 【被引频次】19
  • 【下载频次】334
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