【摘要】 以脂肪醇聚氧乙烯醚(AEO3)为原料,以P2O5为磷酸化试剂,合成了脂肪醇聚氧乙烯醚磷酸酯。考察了P2O5的投料方式、原料配比、酯化时间、酯化温度、搅拌速度对酯化率的影响,确定了最佳酯化条件:在40℃强烈搅拌下,分批加入P2O5,n(AEO3)∶n(P2O5)=3∶1,酯化温度80℃,酯化时间4h。测试表明脂肪醇聚氧乙烯醚磷酸酯的抗静电性能可以满足丙纶纤维的生产需要。更多还原

【Abstract】 Aliphatic alcohol polyethenoxy phosphate is synthesized based on aliphatic alcohol polyethenoxy ether (AEO 3) and phosphorus pentoxide. The effects of the feeding way of phosphorus pentoxide, the ratio of AEO 3 to P 2O 5, the temperature and reaction time on the yield are investigated. The optimum esterification conditions include feeding P 2O 5 in batches at 40℃ with vigorous stirring, n (AEO 3)∶[KG-*2] n (P 2O 5)=3∶[KG-*2]1, keeping the temperature at 80℃ and reaction time for 4h. The results of experiments show that the antistatic of aliphatic alcohol polyethenoxy phosphate can meet the requirements in production of PP fibre更多还原