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中纯度对苯二甲酸合成的PET的流变特性研究

Study on Rheological Performance of PET Synthesized with Medium - purity Terephthalic Acid (MTA)

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【作者】 林耀瞿中凯林生兵

【Author】 Lin Yao (Polyester Division,SINOPEC Shanghai Petrochemical Co. ,Ltd. 200540) Qu Zhongkai Lin Shengbing ( National Engineering Research Center of Synthetic Fibers, Shanghai 200540 )

【机构】 中国石化上海石油化工股份有限公司技术中心合成纤维国家工程研究中心合成纤维国家工程研究中心 200540上海 200540上海 200540

【摘要】 采用毛细管流变仪研究了自制的用中纯度对苯二甲酸(MTA)合成的聚对苯二甲酸乙二醇酯(PET)流变性能。结果表明,用MTA合成的PET熔体属非牛顿假塑性流体,表现为切力变稀且剪切粘度低于常规PET,其非牛顿指数大于常规PET,熔体表观粘度对温度的敏感性也大于常规PET。

【Abstract】 The Rheological property of self - prepared PET synthesized with medium - purity terephthalic acid was studied with capillary rheometer. The result showed that the PET melt synthesized with MTA was non - Newtonian pseudoplastic fluid,which is characterized by the following aspects: its cutting force is turning thinner,its cutting viscosity is lower than conventional PET, its non - Newtonian index is higher than conventional PET, and temperature sensitivity of the melt apparent viscosity of the melt is also stronger than that of conventional PET.

【关键词】 对苯二甲酸流变性中纯度聚酯
【Key words】 terephthalic acidrheological propertymedium - purityPET
  • 【文献出处】 金山油化纤 ,Petrochemical Technology In Jinshan , 编辑部邮箱 ,2005年02期
  • 【分类号】TQ323.4
  • 【被引频次】2
  • 【下载频次】127
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