【摘要】 为研究二烃基二硫代磷酸酯合过渡金属配合物与氮碱加合物的性能,合成了二乙基二硫代磷酸酯合钴（Ⅲ）配合物,利用其与邻菲咯啉的加合反应,得到了Co[（C₂H₅O）₂PS₂]₂(C₁₂H₈N₂)配合物并测定了它的晶体结构.Co（Ⅱ）与2个二硫代磷酸酯的4个硫原子和邻菲咯啉分子中的2个氮原子形成六配位的八面体结构.二硫代磷酸酯分子中的磷原子与2个硫原子2个氧原子形成四面体的结构.更多还原

【Abstract】 To study the properties of the adduct formation of dialkyldithiophosphate coordination compound of intergrade metal with nitrogen base, Co[（C₂H₅O）₂PS₂] were synthesized. Co[（C₂H₅O）₂PS₂]₂（C_<sup>12 H₈N₂） were obtained by adductive reaction between Co[（C₂H₅O）₂PS₂]₃ and phenanthroline. The crystal and molecule structures of title complex were analyzed. The cobalt atom in the title complex has a octahedral geometry with four Co-S bonds and two Co-N bonds. The central atom P is tetrahedrally surrounded by two sulphur atoms and two oxygen atoms in the diethyldithiophosphate ligand.更多还原