【摘要】 用聚氧乙烯(PEO)大分子单体与2-乙烯基吡啶(VP)在苯中以偶氮二异丁腈为引发剂共聚,合成了带规整聚氧乙烯(PEO)支链的聚2-乙烯基吡啶(PVP).接枝共聚粗产物经纯化及用IR,1H NMR和膜渗透压计等表征.研究了共聚条件.结果表明,接枝效率可达到56%,相对分子质量可达6×104.该接枝共聚物呈现一定的乳化性及良好的相转移催化性.它与LiClO4或TCNQ络合后呈现离子导电或电子导电性.其混合导电率明显高于离子导电率及电子导电率,即呈现协同效应.更多还原

【Abstract】 Amphiphilic poly（vinyl pyridine）（PVP） with uniform polyoxyethylene（PEO） was synthesized by copolymerization of the PEO macromer with 2-vinyl pyridine in benzene,using AIBN as initiator.The purified copolymer was characterized by IR,（）¹H NMR and membrane osmometry.The copolymerization conditions were studied.The results showed that the grafting efficiency is able to reach 56?% and molecular weight of the copolymer can reach 6×10⁴.The graft copolymer can,exhibit emulsifying ability and good phase transfer catalytic property in the Williamson reaction.The grafc copolymer after complexed wich LiClO₄ and TCNQ showed ionic conductivity,electronic conductivity and mixed conductivity,respectively.The mixed conductivity showed an obvious synergistic effect.更多还原