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纳米ZnO/TiO2复合颗粒制备及紫外屏蔽性能研究

Preparation of ultra-fine ZnO/TiO2 and characterization of broad spectrum sunscreen

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【作者】 金名惠张家新

【Author】 Jin Minghui Zhang Jiaxin Assoc. Prof.; Dept. of Chemistry, Huazhong Univ. of Sci. & Tech., Wuhan 430074, China.

【机构】 华中科技大学化学系华中科技大学化学系 湖北武汉430074湖北武汉430074

【摘要】 以Ti(SO4)2和Zn(AC)2为原料,在制备金红石型纳米TiO2粉体的基础上,用溶胶凝胶法制得纳米ZnO/TiO2复合粉体.实验结合纳米TiO2和纳米ZnO的优点制得一种广谱防晒剂.TEM显示该复合颗粒为核壳式结构;XRD分析该复合颗粒内核为金红石型TiO2,表面包覆一层六方晶系ZnO且该复合颗粒中存在强的化学键.UVVis测试表明该复合颗粒在整个紫外区的吸收能力达到85%,在UVA(320~400nm)区吸收性能比纯的TiO2强得多.

【Abstract】 The ZnO/TiO2 Composite particles were prepared by sol-gel with Ti(SO42, Zn(AC)2 as raw material. The surface structure of ZnO/TiO2 samples was characterized by IR, TEM, XRD. The result indicates that the average diameter of ZnO/TiO2 is 50?nm. and there is a chemical bond in ZnO and TiO2. The UV shielding characteristic is investigated by UV-Vis. The UV shielding capability of ZnO/TiO2 was higher than that of rutile ultra-fine TiO2 in UVA region, and its shielding rate was to 85?% in UVA and UVB region, that prove the composite particle has a prosperous applied future as a broad spectrum sunscreen.

  • 【文献出处】 华中科技大学学报(自然科学版) ,Journal of Huazhong University of Science and Technology , 编辑部邮箱 ,2005年02期
  • 【分类号】TQ658.24
  • 【被引频次】42
  • 【下载频次】792
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