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热浸镀用锌及锌铝合金的恒电流电化学性能

Electrochemical protection performance of hot-dipping Zn and Zn-Al alloys

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【作者】 李鑫杜鸿雁张杰张胜涛魏绪钧李焰

【Author】 LI Xin1,2, DU Hong–yan3, ZHANG Jie4,5, ZHANG Sheng–tao3, WEI Xu–jun1, LI Yan4 (1. School of Materials and Metallurgy, Northeastern University, Shenyang 110004, China; 2. Beijing General Research Institute of Mining and Metallurgy, Beijng 100044, China; 3. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China; 4. Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; 5. Graduate School of the Chinese Academy of Sciences, Beijing 100039,China)

【机构】 东北大学材料与冶金学院重庆大学化学化工学院中国科学院海洋研究所东北大学材料与冶金学院 辽宁沈阳110004 北京矿冶研究总院北京100044重庆400044山东青岛266071 中国科学院研究生院北京100039辽宁沈阳110004辽宁沈阳110004

【摘要】 在海水腐蚀过程中,热浸镀层金属(或合金)对钢铁基体的阴极保护作用是很重要的因素,只有驱动电位大且稳定、电流效率高、表面腐蚀均匀的镀层才能保证钢材在海水中使用长久。作者按照国标GB/T17848-1999的要求对几种典型的热浸镀用锌及锌铝合金测试了开路电位、工作电位,计算了电流效率,观察了腐蚀产物脱落情况及腐蚀均匀性,评价了各种典型镀层金属(合金)的电化学保护性能。研究表明,Zn的电化学性能最好,Zn-55Al-1.6Si合金的电化学性能最差,Zn-5Al-0.2RE、Zn-5Al-0.1Mg、Zn-6Al-3Mg、Zn-11Al-3Mg-0.2Si、Zn-25Al-0.2Mg-0.2Si和Zn-25Al-0.2RE-0.2Si合金介于二者之间。

【Abstract】 During corrosion process of hot-dip coatings immersed in seawater, cathodic protection by hot dipping zinc and zinc-aluminum alloy coatings to substrate steel is a very important factor. Only the coatings with high and stable driving voltage, high current efficiency and uniform surface corrosion can last long. The electrochemical protection performance of Zn and Zn-Al alloys for hot dip galvanization was examed according to GB/T 17848-1999. The results indicate that Zn showed the best electrochemical performance, Zn-55Al-1.6Si were the worst with many others in between.

【基金】 国家自然科学基金资助项目(40306013)
  • 【分类号】TG174.4
  • 【被引频次】12
  • 【下载频次】216
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