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大豆蛋白接枝苯乙烯的合成及膜性能

Synthesis and film properties of the grafted copolymers of styrene and soy protein isolate~

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【作者】 奚冬雷; 杨成; 刘晓亚; 陈明清; 孙超; 徐玉兰;

【Author】 XI Dong-lei,YANG Cheng,LIU Xiao-ya,CHEN Ming-qing,SUN Chao,XU Yu-lan(School of Chemical and Material Engineering,Southern Yangtze University,Wuxi 214036,China)

【机构】 江南大学化学与材料工程学院; 江南大学化学与材料工程学院 江苏无锡214036; 江苏无锡214036; 江苏无锡214036;

【Abstract】 The grafting of styrene on soy protein isolate (SPI) in 8 moL/L urea aqueous solution initiated by ammonium cerous nitrate-potassium persulfate was studied.The grafted copolymers were characterized by NMR.The results indicated styrene had been grafted on the SPI.The films were prepared from aqueous solutions of soy protein and its grafted copolymer at different pH and various plastizer contents.The tensile strength (TS) and the elongation (E%) of these films were determined.The results indicated that TS values of SPI-g-PSt films were higher than those of SPI films,whereas E values of SPI-g-PSt films were lower than those of SPI films.The results also indicated TS and E of SPI-g-PSt and SPI increased with the increasing of pH and TS of SPI-g-PSt films increased with the increasing of graft percentage of copolymer.

【基金】 国家自然科学基金资助项目(20374025)
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2005年04期
  • 【分类号】TB43
  • 【被引频次】4
  • 【下载频次】161
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