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混合金属氧化物固载杂多酸的制备及催化性能

Studies on preparation and property of heteropolyacid as supported on mixed metal oxides catalyst

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【作者】 余新武石先兴吴进军徐鹏

【Author】 YU Xin-wu,SHI Xian-xing,WU Jin-jun,XU Peng(Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002,China)

【机构】 湖北师范学院化学与环境工程系湖北师范学院化学与环境工程系 湖北黄石435002湖北黄石435002湖北黄石435002

【Abstract】 A new kind of solid acid based on heteropolyacid proved be a useful catalyst in the synthesis of cyclohexyl formate.The new catalyst HPAS/TiO2-WO3 was based on heteropolyacid supported on mixed metal oxides bymicrowave and ultrasonic method. The catalyst was characterized through TEM,TG-DTA,and IR. Data show that catalyst is very active in synthesis reaction of cyclohexyl formate even at mild temperature. Under optimal conditions,the yield of cyclohexyl formate was about 85.4%.

【基金】 湖北省教育厅2001年重点科研项目(2001A06009)
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2005年04期
  • 【分类号】O643.32
  • 【被引频次】15
  • 【下载频次】224
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