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N,N′-二葡萄糖二氨基二苯甲烷苷的合成及其水解研究

Synthesis and hydrolysis of N,N′-Di-D-glucopyranosyldiaminodiphenylmethane

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【作者】 杨德明方志杰

【Author】 YANG De-ming~(1,2),FANG Zhi-jie~1(1.School of Chemical Engineering,Nanjing University of Science & Technology,Nanjing 210094,China;2.Department of Chemical Engineering,Jiangsu polytechnic Universityy,Changzhou 213016,China)

【机构】 南京理工大学化工学院南京理工大学化工学院 江苏南京210094江苏工业学院化工系江苏常州213016江苏南京210094

【Abstract】 The condensation product from D-glucose and N,N’-diamino-diphenyl-methan was prepared and the optimal synthetic conditions were determined;D -Glucose and N,N’-Diamino-diphenyl-methane(1mol∶1mol)were dissolved in anhydrous methanol,reflux raction 25h,yield 53.3%,purity 99.4%,and its structure was characterized by elemental analysis,IR and NMR spectroscopy.The hydrolysis of the condensation product was studied,and results show that the condensation reaction was at equilibrium,and the influence of time and the N,N’-diamino-dimphenyl-methan concentration in water on the hydrolysis were researched.

【基金】 国家自然科学基金资助项目(29972020)
  • 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2005年03期
  • 【分类号】O636.1
  • 【被引频次】3
  • 【下载频次】114
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