节点文献
N,N′-二葡萄糖二氨基二苯甲烷苷的合成及其水解研究
Synthesis and hydrolysis of N,N′-Di-D-glucopyranosyldiaminodiphenylmethane
【Abstract】 The condensation product from D-glucose and N,N’-diamino-diphenyl-methan was prepared and the optimal synthetic conditions were determined;D -Glucose and N,N’-Diamino-diphenyl-methane(1mol∶1mol)were dissolved in anhydrous methanol,reflux raction 25h,yield 53.3%,purity 99.4%,and its structure was characterized by elemental analysis,IR and NMR spectroscopy.The hydrolysis of the condensation product was studied,and results show that the condensation reaction was at equilibrium,and the influence of time and the N,N’-diamino-dimphenyl-methan concentration in water on the hydrolysis were researched.
【关键词】 D-葡萄糖,N,N-二氨基二苯甲烷;
糖番中间体;
合成;
水解;
【Key words】 D-glucose; N,N’-diamino-diphenyl-methane; glycophane intermediate; synthesis; hydrolysis;
【Key words】 D-glucose; N,N’-diamino-diphenyl-methane; glycophane intermediate; synthesis; hydrolysis;
【基金】 国家自然科学基金资助项目(29972020)
- 【文献出处】 化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2005年03期
- 【分类号】O636.1
- 【被引频次】3
- 【下载频次】114