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肼及其衍生物在固体电极上的直接电化学行为研究

Study on direct electrochemical behavior of hydrazine and its derivatives at solid electrodes

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【Author】 MA Jin-fu,GAO Zuo-ning~*,LI Jin-fu(College of Chemistry and Chemical Engineering,Key Lab of EnergySources and Chemical Engineering,Ningxia University,Yinchuan 750021,China)

【机构】宁夏大学化学化工学院；宁夏大学化学化工学院宁夏能源化工重点实验室；宁夏银川750021；宁夏能源化工重点实验室；宁夏银川750021；

【Abstract】 Electrochemical properties of Hydrazine(DH),Phenylhydrazine(PH),p-Nitrophenyldrazine(PNPH) and 2,4-Dinitrophenylhydrzine (DPH)at solid electrodes were investigated.The kinetics parameters(electron transfer coefficient α,diffusion coefficient D and reaction velcoity constant K_f)of the irreversible electrochemical oxidation process were obtained by cyclic voltammetry(CV),chronocoulometry(CC)and chronoamperrometry(CA)at both glassy carbon electrode (GCE)and platinum one,and the absorption behaviors of pH at GCE was studied as well.更多还原

【关键词】肼及其衍生物；电极材料；电化学行为；吸附；
【Key words】 hydrazine and its derivatives； electrode material； electrochemical behaviors； absorption；

【基金】宁夏自然科学基金(E1001);宁夏高等学校科学研究项目(210,0420);宁夏大学自然基金(032211)资助项目

【文献出处】化学研究与应用 ,Chemical Research and Application , 编辑部邮箱 ,2005年03期

【分类号】O646.54
【被引频次】4
【下载频次】144

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