【摘要】 合成了N,N′-二(5-氯水杨醛)缩乙二胺合铜配合物([Cu(5-ClSalen)]),用单晶X射线衍射法测定了晶体结构.其晶体属三斜晶系,空间群P-1,晶胞参数a=0.83285(1)nm,b=0.95170(4)nm,c=1.09304(4)nm,α=115.130(2)°,β=94.694(2)°,γ=101.127(2)°,V=0.75642(4)nm3,分子式C16H12Cl2CuN2O2,Mr=398.72,Z=2,Dc=1.751g/cm3.在配合物中,Cu处于两个氮原子和两个酚氧原子形成的平面四方场中.更多还原

【Abstract】 A complex of copper and N,N’bis(5chlorosalicylidene)ethylenediamine was synthesized and its crystal structure was determined by singlecrystal Xray diffraction method. The crystal belongs to triclinic system, space group P1- with a=0.832 85(1) nm, b=0.951 70(4) nm, c=1.093 04(4) nm, α=115.130(2)°, β=94.694(2)°, γ=101.127(2)°,V=0.756 42(4) nm 3, formula C_ 16H_ 12Cl_ 2CuN_ 2O_ 2, M_ r=398.72, Z=2,Dc=1.751 g/cm 3. In the complex, the copper atom is coordinated by two nitrogen atoms and two phenolic oxygen atoms in a squareplane manner.更多还原