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酸性品红退色光度法测定微量溴酸根离子的研究

Study on spectrophotometric determination of micro amount of BrO3- by oxidation decoloration of acid fuchsin

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【作者】 罗道成刘俊峰宋和付

【Author】 LUO Dao-cheng~*,LIU Jun-feng,SONG He-fu (College of Chemistry and Chemical Engineering,Hunan University of Science and Technology,Xiangtan 411201,China),Huaxue Shiji,2005,27(5),299~300

【机构】 湖南科技大学化学化工学院湖南科技大学化学化工学院 湖南湘潭411201湖南湘潭411201湖南湘潭411201

【摘要】 研究了在硫酸介质中,在硫酸钠的催化作用下,溴酸根离子氧化酸性品红的最佳反应条件。退色溶液的最大吸收波长为575nm,表观摩尔吸光系数为1.32×105L·mol-1·cm-1,溴酸根离子在3.0~18μg/25mL范围内符合比尔定律。该法用于化学试剂中微量溴酸根离子的测定,获得了满意的结果。

【Abstract】 The optimum reaction conditions for oxidation of acid fuchsin in a sulfuric acid medium by BrO-3 with sodium sulfate as the catalyst were studied.The maximum absorption wavelength of the decoloring solution was 575nm with a molar absorptivity of 1.32×105 L·mol-1·cm-1,and the linear range was 3.0~18μg/25mL of BrO-3.The method was applied to the determination of micro amount of BrO-3 in chemical reagents with satisfactory results.

  • 【分类号】O657.32
  • 【被引频次】23
  • 【下载频次】248
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