【摘要】 利用苄基氯和锡反应,合成了一维链状有机锡化合物(PhCH2)3SnCl。通过元素分析、红外光谱和核磁共振氢谱对其结构进行了表征。用X射线单晶衍射测定了该化合物的晶体和分子结构。锡原子呈畸变四面体构型。通过化合物分子间Sn…Cl作用,形成一维链状结构。更多还原

【Abstract】 One-dimensional chain organotin compound （PhCH₂）₃SnCl has been synthesized by the reaction of PhCH₂Cl with Sn and characterized by elemental analysis,IR and （（）¹HNMR）.The crystal and molecular structure were determined by X-ray single crystal diffraction.In this compound,the tin atom has distorted tetrahedral configuration.The molecules are packed in the unit cell in one-dimensional chain structure through a weak interaction between the chlorine atom and tin atom of an adjacent molecule.更多还原