【摘要】 对金属卟啉化合物在催化氧化反应中的应用和机理方面的最新研究成果进行了详细的阐述,并概述了量化计算方法在金属卟啉分子设计、结构及催化活性等方面的应用。也介绍了本课题组在上述领域的最新研究成果。预测了金属卟啉化合物在催化领域的应用前景。更多还原

【Abstract】 The applications and mechanism of metalloporphyrins in catalytic oxidation are discussed. Quantum calculation method used in molecular design,uncovering relation between structure and catalytic activity of metalloporphyrins is reviewed. Recent works of authors’ research group are also introduced. The future application of metalloporphyrins in catalysis is prospected.更多还原