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天然沸石粉阳离子吸附性能分析方法的探讨

DISCUSSION ON DETERMINATION OF EXCHANGEABLE BASIC CATIONS AND CATION EXCHANGE CAPACITY OF ZEOLITIC ROCK POWDER

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【作者】 卢文洲林初夏刘勇

【Author】 Lu Wenzhou, Lin Chuxia, Liu Yong (College of Resources and Environment, South China Agricultural University, Guangzhou 510642, China)

【机构】 华南农业大学资源环境学院华南农业大学资源环境学院 广州510642广州510642广州510642

【摘要】 通过比较不同浓度的NH4Ac溶液对天然沸石粉所吸附的碱金属和碱土金属离子多次连续提取的效果,将由交换性K+、Na+、Ca2+和Mg2+加和所获得的阳离子交换量与由常规土壤阳离子交换量测定法获得的阳离子交换量进行比较,发现常规的土壤分析方法不适于测定天然沸石粉所吸附的交换性K+、Na+、Ca2+和Mg2+及阳离子交换量。建议用K+、Na+、Ca2+和Mg2+5次提取总量分别作为天然沸石粉所吸附的交换性K+、Na+、Ca2+和Mg2+的估算值,并把其提取量加和作为沸石粉阳离子交换量的估算值。

【Abstract】 An experiment was conducted to compare the effects of varying concentrations of NH4Ac solutions on the successive extraction of exchangeable K +, Na +, Ca 2+ and Mg 2+ in zeolitic rock powder. The method of the cumulative basic cations sum to get cation exchange capacity (CEC) was compared with the traditional method for soil CEC measurement. The results suggested that the traditional soil analytical methods were not suitable for the determination of exchangeable basic cations and cation exchange capacity of zeolitic rock powder. Based on the current experimental results, a new analytical procedure was proposed for the measurements of exchangeable basic cations and cation exchange capacity of the zeolitic rock powder.

【基金】 美国Expressway InternationalLtd.资助项目(4200-H03025);华南农业大学校长基金项目(2003S015)
  • 【文献出处】 化学分析计量 ,Chemical Analysis and Meterage , 编辑部邮箱 ,2005年03期
  • 【分类号】O647.331
  • 【被引频次】9
  • 【下载频次】299
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