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NVP-HEMA-KH570共聚水凝胶的合成及其溶胀性能研究

Synthesis of Polyhydrogel NVP-HEMA-KH570 and Study on its Ability of Swelling and Dehydration

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【作者】 蔡立彬崔英德黎新明王颖媚叶凯贞

【Author】 CA1 Li-bin, CUI Ying-de, LI Xin-ming, WANG Ying-mei, YE Kai-zhen (School of Materials Science and Engineering, Northwesrern Polytechnical University, Xi’ an 710072, Shanxi, China; Institute of Green Chemical Engineering, Zhongkai University of Agricure and Technology, Guangzhou 510225, Guangdong, China; 3 Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510090, Guangdong, China)

【机构】 西北工业大学材料学院仲恺农业技术学院绿色化工研究所广东工业大学轻工化工学院广东工业大学轻工化工学院 陕西 西安 710071广东 广州 510225广东 广州 510090广东 广州 510090

【摘要】 以N,N’-亚甲基双丙烯酰胺为交联剂,偶氮二异丁氰(AIBN)为引发剂,合成不溶于水的乙烯吡咯烷酮(NVP)/甲基丙烯酸β-羟乙酯(HEMA)/γ-(甲基丙烯酰氧)丙基三甲氧基硅烷(KH-570)共聚水凝胶,研究了PVP水凝胶的平衡溶胀度及脱水性能。结果表明,随着NVP在水凝胶中含量的增大,水凝胶的平衡溶胀度逐渐增大;环境温度升高,KH570、BIS的含量及浸泡溶液的离子浓度增大,水凝胶的平衡溶胀度逐渐减少;在相同的时间内,环境温度越高,水凝胶的脱水率也越大;在同一温度下,HE-MA含量越大,凝胶脱水的速度就越慢,而浸泡的溶液离子浓度越高,脱水率就越大。

【Abstract】 In this paper, the N-vinylpyrrolidone( NVP) , PVP, and KH-570 are synthesized with crosslinker (N, N’-methylene-bis-acrylamide) and initiator( AIBN) . Meanwhile, equilibrium water content( EWC) and dehydration rate are also researched. The result shows that when the content of NVP in the hydrogel increases, EWC increases too. EWC decrease when the environment’ s temperature, the content of KH-570 and BIS and the solution’ s ion concentration increase. Also, the higher the temperature of the environment and the ratio of main components , the dehydration of hydrogel is bigger. And also the dehydration is proportional to the concentration of solution that is used to soak the hydrogel.

  • 【文献出处】 合成材料老化与应用 ,Synthetic Materials Aging and Application , 编辑部邮箱 ,2005年03期
  • 【分类号】TQ427.1
  • 【被引频次】1
  • 【下载频次】337
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