【摘要】 以二氟碳基锡氧化物(n-C6F13CH2CH2)2SnO,二正丁基锡氧化物(n-C4H9)2SnO和不同结构的芳香羧酸ArCOOH为原料,较高产率(68%~95%)地合成了尚未见文献报道的7种二烃基锡羧酸酯类化合物,并对这些化合物进行了表征.这些化合物属于两种构型{[R2Sn(OOCAr)]2O}2(A)和R2Sn(OOCAr)2(B),在这两类化合物(A)和(B)中,中心锡原子具有不同的配位形式和配位数.更多还原

【Abstract】 Seven organotin carboxylate compounds not yet published in any document were synthesized through the reaction of difluoroalkyltin oxide (n-C₆F₁₃CH₂CH₂)₂SnO or dibutyltin oxide （n-C₄H₉）₂SnO with ArCOOH with high yields （68%～95%）, and these compounds were characterized with （）¹H NMR. These compounds were classified into two types of structures: ｛[R₂Sn（OOCAr）]₂ O｝₂ （A） and R₂Sn（OOCAr）₂ （B）. The central stannnic atoms in A and B types possessed different coordinate models and coordinate numbers.更多还原