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纳米生态建筑涂料光催化降解甲醛的研究

Study on photocatalytic degradation of gaseous formaldehyde by building eco-coating

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【作者】 耿启金王西奎孙效正张建富

【Author】 Geng Qijin 1, Wang Xikui 2, Sun Xiaozheng 1, Zhang Jianfu 3. (1.Chemistry Department of Weifang College, Weifang Shandong 261061;2.School of Chemical and Engineering of Jinan University, Jinan Shandong 250022;3.Weifang Jingrui Chemical Factory, Weifang Shandong 261061)

【机构】 潍坊学院化学系济南大学化学化工学院潍坊市精锐化工厂 山东潍坊261061山东济南250022山东潍坊261061山东潍坊261061

【摘要】 以掺加纳米TiO2制备的光催化建筑涂料为催化剂,研究了在紫外光照条件下对气态甲醛的催化降解,并探讨了纳米催化剂晶型、用量和吸附量对光催化降解甲醛的影响。实验结果表明,锐钛型纳米TiO2具有较高的光催化降解甲醛的活性,1h甲醛的降解率可达到70%左右,产物主要为二氧化碳和水;光催化降解甲醛受到涂膜上吸附量的较大影响;该涂料对甲醛的光催化降解反应表现出一级动力学速率规律,且具有良好的线性关系。

【Abstract】 The photocatalytic degradation of gaseous formaldehyde has been investigated by using nano-TiO_ 2particles supported on building eco-coating as the catalyst under the illumination of UV-light. Experiments were conducted by changing the concentration of catalyst and the adsorption of formaldehyde on coating, the formaldehyde was detected by spetrophotometry and GC. It is proved that the anatase nano-TiO_ 2 is one of excellent catalysts, and formaldehyde can be degraded completely under illumination of UV-light. It was also proved that the reaction order of the group was first order.

【基金】 山东省自然科学基金重点资助项目(No.Z2000B01)。
  • 【文献出处】 环境污染与防治 ,Environmental Pollution & Control , 编辑部邮箱 ,2005年07期
  • 【分类号】X512;TU561;
  • 【被引频次】17
  • 【下载频次】485
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