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环氧乙烷合成反应器温度-时间优化策略

Optimal temperature-time policy of ethylene oxide synthesis reactor

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【作者】 黄琦王弘轼凌泽济

【Author】 HUANG Qi~1,WANG Hongshi~1,LING Zeji~2 (~1Department of Chemical Engineering, East China University of Science and Techology,Shanghai 200237,China; ~2Yangzi Petrochemical Academy, Nanjing 210048,Jiangsu,China)

【机构】 华东理工大学化工系扬子石化研究院 上海200237上海200237江苏南京210048

【摘要】 根据工业实际生产数据反算得到能够反映催化剂失活特性的银催化剂失活动力学方程. 在失活模型基础上, 对环氧乙烷合成反应器的管外沸腾水温度时间策略进行优化, 得到最优沸腾水升温曲线, 从而提高环氧乙烷反应的经济效益. 对同系列新型催化剂的反应器操作优化提出了可行的研究方法.

【Abstract】 The deactivation kinetics equations of ethylene oxide synthesis silver catalyst were obtained from the calculation of real industrial data.The equations could represent the characteristics of catalyst deactivation. On the basis of the deactivation model, the boiling water temperature-time policy of ethylene oxide synthesis reactor was optimized.The optimal curve of boiling water temperature was obtained.It could enhance the economic benefits of ethylene oxide synthesis.Feasible approaches to optimizing reactor temperature of the same series of new catalysts were recommended.

  • 【文献出处】 化工学报 ,Journal of Chemical Industry and Engineering(China) , 编辑部邮箱 ,2005年05期
  • 【分类号】TQ223.24
  • 【被引频次】1
  • 【下载频次】250
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