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十二烷基苯磺酸钠表面膜的扩张粘弹性质研究

Dilatationai Viscoelasticity of Surface Film of SDBS at Gas-Water Interface

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【作者】 程栋; 丁洪流; 陆维昌; 刘启贞; 陈邦林;

【Author】 CHENG Dong DING Hong-liu LU Wei-chang LIU Qi-zhen CHEN Bang-lin (Department of Chemistry,East China Normal University,Shanghai 200062,China)

【机构】 华东师范大学化学系; 华东师范大学化学系 上海200062; 上海200062;

【摘要】 研究了不同浓度十二烷基苯磺酸钠(SDBS)溶液在气-液表面上的扩张粘弹性质,讨论了扩张模量、扩张粘度、扩张模量的相角随频率的变化规律,实验结果表明,其表面膜的微观弛豫过程主要受扩散弛豫类型控制.还讨论了温度、浓度等因素对 SDBS 表面扩张性质的影响,研究了它们的内在联系.

【Abstract】 The dilational viscoelasticity properties of gas-water interface of SDBS were investigated.The dependence of dilational modulus,dilational viscosity and phase angle on dilational frequency was expoun- ded.The results showed that the microscopic relaxation model of the surface film was decided by diffusion- control model.Besides,the influence of temperature and concentration to the interfacial dilational properties of SDBS was also discussed,and the intrinsic relation between them was studied.

  • 【文献出处】 华东师范大学学报(自然科学版) ,Journal of East China Normal University(Natural Science) , 编辑部邮箱 ,2005年04期
  • 【分类号】O647.1
  • 【被引频次】13
  • 【下载频次】436
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