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UHMWPE/CNTs冻胶体系的流变行为研究

Study on the rheological behavior of oltra-high molecular weight polyethylene/carbon nanotubes gel

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【作者】 王新鹏梁琳俐王燕萍王依民江若平

【Author】 WANG Xing-peng, LIANG Yan-ping,WANG Yi-min, JIANG Ruo-ping College of Material Science and Engineering,Donghua University, Shanghai 200051, China The Shanghai Petrochemical Company Limited,Shanghai 200540, China

【机构】 东华大学材料科学与工程学院中国石化上海石化股份有限公司 上海 200051上海 200051上海 200540

【摘要】 研究了碳纳米管(CNTs)的加入对超高分子质量聚乙烯(UHMWPE)稳态表观粘度、粘流活化能、非牛顿指数和结构粘度指数的影响。结果表明:碳纳米管添加量小于或等于3ω时,UHMWPE/CNTs冻胶体系的粘流括化能降低,表观粘度都低于空白UHMWPE冻胶体系。CNTs的加入对UHMWPE冻胶体系的非牛顿指数和结构粘度指数影响不大。

【Abstract】 In this paper the influence of carbon nanotubes(CNTs) on the apparent viscidity, the energy of viscidity, the non-Newtonian index and the structural viscidity index of Ultra-high molecular weight polyethylene were studied. It was found when the content of carbon nanotubes(CNTs) is lower than 3 w, the viscidity and the energy of viscidity of the UHMWPE/CNTs gel are all lower than that of pure UHMWPE gel. CNTs has very little influence on the non-Newtonian index and the structural viscidity index of the UHMWPE/CNTs gel, that is to say it has little influence on the gel-spining of UHMWPE/carbon nanotubes composite fiber.

  • 【文献出处】 合成技术及应用 ,Synthetic Technology and Application , 编辑部邮箱 ,2005年02期
  • 【分类号】TQ325.12
  • 【被引频次】8
  • 【下载频次】116
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