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麦秸快速热解的试验研究

Study on Fast Pyrolysis of Wheat Straw in a Spouted Bed Reactor

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【作者】 杨昌炎丁一刚刘生鹏姚建中林伟刚

【Author】 YANG Chang-yan~(1,2),DING Yi-gang~(2),LIU Sheng-peng~(2),YAO Jian-zhong~(1),LIN Wei-gang~(1)(1. Multiphase Reaction Laboratory, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China; 2. Hubei Key Lab of Novel Reactor & Green Chemical Technology, Wuhan Institute of Chemical Technology, Wuhan 430073,China)

【机构】 中国科学院过程工程研究所多相室武汉化工学院化工与制药学院湖北省新型反应器与绿色化工重点实验室中国科学院过程工程研究所多相室 北京100080湖北武汉430073北京100080北京100080

【摘要】 介绍了喷动流化床(喷动床)快速热解试验装置及方法,研究了主要影响因素———热解温度对麦秸热解气、液、固三种产品的产率和热解气成分的影响,采用色-质谱联用仪(GC-MS)分析了热解液成分。结果表明,热解温度为460~520℃时热解油产率最大,主要有醋酸、羟基乙醛、羟基丙酮、左旋葡聚糖、糠醛,油热值为17.0MJ.kg-1;热解气主要为CO2和CO,还含有少量H2、CH4和C2~C4的烯烃。

【Abstract】 This paper introduced the fast pyrolysis of wheat straw in a spouted bed reactor. A key parameter pyrolysis temperature was studied for the production of gases, liquid and chars from the fast pyrolysis of wheat straw. The experimental results showed that the maximum liquid yield is about 60%(daf.) at the range from 460℃ to 520℃. The bio-oil was composed of acetic acid, hydroxyacetaldehy, acetol, levoglucosan, furaldehyde, and a small quantity of phenols. The heating value of bio-oil from the fast pyrolysis of wheat straw was about 17.0 MJ·kg-1. The gases form wheat straw pyrolysis consisted of CO2, CO, CH4, H2, and a little of alkenes.

【关键词】 麦秸喷动床快速热解热解油
【Key words】 wheat strawspouted bed reactorfast pyrolysisbio-oil
【基金】 国家重点基础规划(973)资助项目(2004CB719700);国家863计划资助项目(2003AA514023)
  • 【分类号】TQ914.1
  • 【被引频次】32
  • 【下载频次】282
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