【摘要】 利用(R,R)-环己二胺和5-苄氧基-3-叔丁基水杨醛反应合成了手性Salen配体,将该配体与过渡金属Mn3+,Fe3+,Co2+,Ni2+络合制备了手性Salen金属配合物,并用红外,核磁,元素分析对配合物结构进行表征.更多还原

【Abstract】 A novel chiral Salen ligand was synthesized by the reaction of 5-benzyloxy-3-tert-butyl salicylaldehyde with(R,R)-1,2-diaminocyclohexane.From this ligand,several Salen-metal(Mn3+,Fe3+,Co2+,Ni2+) complexes were prepared.Their structures were characterized by FT-IR,elemental analysis and 1H NMR.更多还原