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沉积亚单层荧光染料提高有机发光器件的发光效率
Improving the Efficiency of Organic Light-Emitting Devices with a Quinacridone Sub-Monolayer
【摘要】 结合掺杂薄层作为发光探针层的方法和亚单层(submonolayer)有机发光技术,利用沉积在有机发光器件发光层中的亚单层奎丫啶酮(Quinacridone,QAD)分子作为探针,同时改变QAD层的位置,对有机发光器件中激子的形成与扩散进行了研究,器件结构为ITO/NPB(60nm)/Alq3(xnm)/QAD(0.05nm)/Alq3[(60-x)nm]/LiF/Al(其中x=0,2.5,5,7.5nm).通过对各器件不同条件下的电致发光谱、发光强度和发光效率的对比研究,得到在x=5nm处引入亚单层QAD可以使QAD分子通过能量转移而获得的激子数量最多,进而可以实现高效率的发光.
【Abstract】 A Quinacridone(QAD) sub-monolayer was inserted in the Electron transporting layer of Organic Light-emitting Devices(OLEDs),which was used as a probe for excitons′ formation and diffusion.Tthe devices configuration are ITO/NPB(60 nm)/Alq3(x nm)/QAD(0.05 nm)/Alq3[(60-x)nm]/ LiF(0.4 nm)/Al(180 nm),of which x=0, 2.5, 5, 7.5 nm is the different position of deposited QAD sub-monolayer. The electroluminescence (EL) spectra and intensity of these four devices show that QAD sub-monolayer located at 5 nm apart from the NPB/Alq3 heterojunction interface obtained excitons from Alq3 at most through frster energy transfer.The comparison of the efficiency-operating voltage characteristics of the devices also indicate this result.
【Key words】 Organic light-emitting devices; Sub-monolayer; Quinacridone; Exciton; Energy transfer;
- 【文献出处】 光子学报 ,Acta Photonica Sinica , 编辑部邮箱 ,2005年08期
- 【分类号】TN383.1
- 【被引频次】5
- 【下载频次】81