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壳聚糖-双氰胺脱色剂的合成和应用

Synthesis and application of chitosan - dicyandiamine decolouriser

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【作者】 安忠军黄克玲鲁航文岳中刘维屏

【Author】 An Zhongjun1, Huang Keling1, Lu Hang2, Wen Yuezhong1, Liu Weiping1 (1. Research Institute of Environmental Science, Zhejiang University,Hangzhou 310027, China; 2. Zhejiang Research Institute of Environmental Protection, Hangzhou 310007, China)

【机构】 浙江大学环境科学研究所浙江省环境保护科学研究院浙江大学环境科学研究所 浙江杭州310027浙江杭州310027浙江杭州310007浙江杭州310027

【摘要】 以壳聚糖、双氰胺为主要原料合成了一种新型、高效的脱色剂处理染料废水,该脱色剂对4种典型的染料的脱色率都>90%。实验表明:当合成温度控制在约50℃、n(壳聚糖结构单元)∶n(双氰胺)∶n(硫酸铝)=1∶4∶1.5、反应时间为2.5h时,合成的脱色剂对染料废水的脱色效果为最佳。实验发现该脱色剂对染料废水的脱色率要远远高于壳聚糖与硫酸铝的复配溶液。对上虞污水厂废水的处理效果,其COD去除率比使用PAC提高20%以上。

【Abstract】 A new kind of highly efficient decolouriser has been synthesiz ed with chitosan- dicyandiamine as main raw material to treat the dye wastewater . The decolorization rates of the 4 typical types of dye-stuff (500 mg/L)unde r the tests are all over 90%. The results of experiments show that under the con ditions of the reaction temperature is 50 ℃, n(chitosan) ∶ n(dicyandiamine ) ∶ n(aluminum sulfate) = 1 ∶ 4 ∶ 1.5, reaction time is 2.5 h, the decol orization rates are the best. The results show that the decolorization rates of chitosan - dicyandiamine decolouriser are much higher than chitosan, which is u sed in combination with aluminum sulfate. The treatment effect to wastewater of Shangyu Wastewater Factory has been studied. The result indicates that the COD r emoval rate is 20% higher than PAC, which was used in the past in this factory.

【关键词】 壳聚糖双氰胺脱色剂染料废水
【Key words】 chitosandicyandiaminedecolouriserdye wastewater
【基金】 浙江省科技计划重点科研项目,编号:2003C23018
  • 【文献出处】 工业水处理 ,Industrial Water Treatment , 编辑部邮箱 ,2005年06期
  • 【分类号】X788
  • 【被引频次】6
  • 【下载频次】279
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