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Eu(Ⅲ)(CH2OHCOO)3·2H2O和Eu(Ⅲ)(CH2OHCOO)3·phen·H2O配合物的合成和表征
Synthesis and Characteriztion of Eu(Ⅲ) Binary and Ternary with Glycollic Acid and 1,10-phenanthroline
【摘要】 用羟基乙酸与稀土元素Eu(Ⅲ)合成了二元配合物,又用羟基乙酸、邻菲啰啉与Eu(Ⅲ)合成了三元配合物.通过元素分析、红外光谱、X射线粉末衍射、热谱、荧光光谱及紫外光谱等测试手段,对其性质进行了研究,从而确定了配合物的组成和结构.
【Abstract】 In this paper binary and tertiary of Eu(Ⅲ) with glycollic acid and 1,10-phenanthroline in aqueous solution were synthesized,and their elements analyses,infrared spectrum,X-ray powder diffraction,thermal analysis,fluorescence spectrum and ultraviolet spectrum have been investigated.The composition of binary Eu(Ⅲ)(CH2OHCOO)3(·2H2O) and tertiary complexes Eu(Ⅲ)(CH2OHCOO)3(·phen·H2O) have been ascertained.
- 【文献出处】 甘肃联合大学学报(自然科学版) ,Journal of Gansu Education College(Natural Science Edition) , 编辑部邮箱 ,2005年03期
- 【分类号】O627.33
- 【下载频次】86