节点文献

苯甲酰水杨酸铽的合成与发光特性研究

Luminescence Properties of Rare Earth Complexes Tb（BSA）₄

推荐 CAJ下载
PDF下载
不支持迅雷等下载工具，请取消加速工具后下载。

【Author】 LIN Peng, LIANG Chun-jun, DENG Zhen-bo, BAI Feng , ZHANG Zhi-feng, XIONG De- ping, ZHANG Xi-qingInstitute of Optoelectronic Technology, Laboratory of Materials for Information Storage and Display, Beijing Jiaotong University, Beijing 100044, China

【机构】北京交通大学光电子技术研究所信息存储、显示与材料开放实验室；北京交通大学光电子技术研究所信息存储、显示与材料开放实验室北京100044；北京100044；北京100044；

【摘要】合成了一类以苯甲酰水杨酸(BenzoylSalicylicAcid,BSA)为配体的稀土铽配合物,将导电高分子材料PVK引入到配合物中,制成了结构为ITO PVK :Tb(BSA) 4 LiF Al的电致发光器件。并对该配合物的吸收特性及电致发光和光致发光性能进行了研究,实验数据表明,在PVK与Tb(BSA) 4之间存在着能量传递,在电致发光中,PVK的发光完全被抑制,这与光致发光的表现不同,这是由于两种发光(光致和电致)机理不同造成的。文章同时比较了几种不同PVK掺杂浓度对于器件性能的影响。更多还原

【Abstract】 A new rare earth complex Tb（BSA）₄ was synthesized and studied. Pure green and narrow band emission was generated from the device with structure ITO/PVK:Tb（BSA ）₄/Alq₃/LiF/Al, where PVK was used to improve the film-formation and hole- transport property of the Tb（BSA）₄. The absorption mechanism, and the photolum inescence and electroluminescence mechanisms are discussed. It has been proved that there exists energy transfer from PVK to Tb（BSA）₄ and the mechanisms of photo luminescence and electroluminescence are different. The effect of different rati os of PVK on the device characteristics is also studied.更多还原