【摘要】 概述了醋酸乙烯酯单体可控/活性自由基聚合的现状。总结了氮氧化合物存在下的聚合、原子转移自由基聚合、可逆加成断裂链转移聚合以及含碘化合物的衰减链转移聚合这四种活性自由基聚合方法用于醋酸乙烯酯聚合的研究结果,并对这四种方法作了简要的比较。更多还原

【Abstract】 This article summarized controlled/living radical polymerization (LRP/CRP) of vinyl acetate (VAc). The four LRP/CRP methods, atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), reversible addition fragmentation chain transfer polymerization (RAFT), degenerative transfer polymerization (DT), were described and briefly compared in the LRP/CRP of VAc.更多还原