【摘要】 采用甘氨酸-硝酸盐燃烧法制备出(CeO2)1-2x(Sm2O3)x固体电解质(简记作SDC)薄膜,以Ni-SDC、Ag分别作为固体氧化物燃料电池阳、阴极。在中温(650~750℃)条件下,该燃料电池对含H2S有害气体的脱除率最高可达到45%。在电流密度-电压(电功率密度)特性曲线中,当Sm∶Ce=2∶8时,作为氢源的H2S气体可使电池的开路电压为0.59V,电功率密度最高达到6.2mW/cm2。Ni-SDC可作为H2S-O2此类燃料电池的阳极替代材料。更多还原

【Abstract】 Glycine-nitrate combustion process（abbr,GNP） was adopted to prepare（CeO₂）_1-2x（Sm₂O₃）_x（abbr,SDC） electrolyte membrane.In the range of 650～750℃,the removal of H₂S was up to 45% while 10%H₂S+90%N₂ flow was used as anode fuel and air as cathode feed in the configuration such as Ni-SDC/SDC/Ag.On the other hand,the open circuit voltage was 0.59V and the maximum power density was 6.2mW/cm² respectively in the SOFC configuration concerned above when the solid electrolyte composition ratio of Sm to Ce was equal to 0.2∶0.8.As a preliminary result,a Ni-SDC anode was a alternative material for H₂S-air SOFC.更多还原