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一种基于照明目的的有机白光发光二极管

A white organic light-emitting diode based on illumination

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【作者】 李明涛李文连徐茂梁魏晗志车广波陈丽莉初蓓张志强胡知之

【Author】 LI Ming-tao~(1,2),LI Wen-lian~1,XU Mao-liang,WEI Han-zhi~1,CHE Guang-bo~1,CHEN Li-li~1,CHU Bei~1,ZHANG Zhi-qiang~3,HU Zhizhi~3(1.Key Laboratory of Excited State Processes,Changchun Institute of Optics,Fine Mechanics and Physics,Chinese Academy of Sciences,Changchun 130033,China;2.Graduate School of the Chinese Academy of Sciences,Beijing 100039,China;3.Organic Photoelectronic Materials & Technology Development Center,Anshan University of Science and Technology,Anshan 114000,China)

【机构】 中国科学院长春光学精密机械与物理研究所激发态物理重点实验室鞍山科技大学有机光电子材料技术发展中心鞍山科技大学有机光电子材料技术发展中心 吉林长春130033中国科学院研究生院北京100039吉林长春130033吉林长春130033辽宁鞍山114000辽宁鞍山114000

【摘要】 研制了一种以照明为目标的有机白光发光二极管(WOLED),该二极管在8V时的色度坐标为(x=0.319,y=0.337),对应的显色指数(Ra)为85.4,色温(Tc)为6151K。该二极管是含NPB和CBP两个基质的多层掺杂型结构器件;此外,NPB{4,4-′bis[N-(1-naphthyl)-N-phenylamino]biphenyl}除了用作绿光和黄光基质外,还用作空穴传输材料,CBP{4,4-′N,N′-dicarbazole-biphenyl}用作红光磷光配合物的基质材料。3个掺杂层分别提供白光发射的红、黄和绿光成分,而蓝光成分则来自于空穴传输层NPB本身的发射。该器件在直流电流密度为0.1mA/cm2时最大白光发光效率可达5.6cd/A(3.9lm/W),在15V时达到的最大亮度为5100cd/m2。其性能参数达到了白光照明光源的要求。

【Abstract】 A white organic light-emitting diode(WOLED) based on illumination was fabricated.The color coordinates of(x=0.319,y=0.337)was obtained at 8V,and the corresponding color rendering index(R_a) and color temperature(Tc) were 85.4 and 6151K,respectively.In this multilayer diode,NPB {4,4′-bis[N-(1-naphthyl)-N-phenylamino]biphenyl} was used as hole-transporting material and host material for green and yellow fluorescent dye,respectively,and CBP {4,4′-N,N′-dicarbazole-biphenyl} was used as host for red emitting Ir-complex.The emission spectrum is composed of red,yellow,green spectral components from each doped layer and blue spectral component from the hole-transporting layer(NPB).The peak luminous efficiency of 5.6cd/A(3.9lm/W) was achieved at 0.1mA/cm~2 and maximum brightness of 5100cd/m~2 was obtained at 15V.The performances of this diode can meet the request of white light based on illumination.

【基金】 国家自然科学基金资助项目(90201012)
  • 【文献出处】 功能材料 ,Journal of Functional Materials , 编辑部邮箱 ,2005年07期
  • 【分类号】TN312.8;
  • 【被引频次】6
  • 【下载频次】257
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