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炉内高温喷射尿素溶液脱硝机理及其影响因素

Mechanism and Parameters Study on NO_x Abatement Use Urea as Agent in Boiler

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【作者】 高亮王智化凌忠钱周樟华李国能周昊岑可法

【Author】 GAO Liang, WANG Zhi-hua, LING Zhong-qian, ZHOU Zhang-hua, LI Guo-neng, ZHOU Hao, CEN Ke-faClean Energy and Environment Engineering Key Lab of Ministry of Education, Institute for Thermal Power Engineering of Zhejiang University, Hangzhou 310027, China

【机构】 浙江大学热能工程研究所能源洁净利用与环境工程教育部重点实验室浙江大学热能工程研究所能源洁净利用与环境工程教育部重点实验室 浙江杭州310027浙江杭州310027浙江杭州310027

【摘要】 试验采用多功能一维沉降炉试验台。模拟电厂锅炉喷射尿素溶液还原烟气中的 NOx 气体成分,采用的方式为尿素溶液 SNCR方式脱硝。试验研究结果分析得到结论为:尿素溶液的最佳喷入温度为 850 ℃~950 ℃,反应的停留时间为 0. 7 s~ 1 s,合理的 NH3 /NO 比例在 1. 5 ~ 3. 0 左右。烟气中的CO、O2 存在对脱硝效果的影响不能忽略,O2 的含量过高不利于脱硝的反应发生, CO在低温条件下有助于脱硝反应中的 NO还原,在高温情况下抑制 NO的还原,总体上讲 CO的存在使反应的“温度窗口”向低温方向移动。

【Abstract】 Experiment was carried out in a one dimension drop tube furnace to simulate urea injected into power plant for NO x reduction. The simulated boiler flue gas and initial NO x were burned with NH 3 and liquid petroleum gas. Results show that the optimal temperature for injected aqueous urea is 850 ℃~950 ℃ and the resident time is about 0.7 s~1 s; NH 3/NO mole ratio should between 1.5 and 3.0. CO and O 2 in flue gas have important influence on the NO x reduction process. Excessive O 2 concentration has negative effects on the NO x deoxidization. CO can improve NO x reduction efficiency at lower temperature, but restrain it at higher temperature. The overall effect is that the “temperature window” will move towards lower temperature because of CO existence.

【关键词】 尿素溶液SNCR停留时间NH/NO摩尔比
【Key words】 aqueous ureaSNCRresident timeNH 3/NO mole ratio
  • 【分类号】X701
  • 【被引频次】63
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