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丙烯酸环氧单酯的合成及光-热固化性能

PREPARATION AND PROPERTIES OF UV-CURABLE AND HEAT-CURABLE EPOXY ACRYLATE

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【作者】 刘红波余林梁陈鸣才何涛王志霞

【Author】 LIU Hong-bo~(1,3), YU Lin-liang~2, CHEN Ming-cai~3, HE Tao~3, WANG Zhi-xia~3 (1.Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China; 2.South China Agricultural University, College of Sciences, Guangzhou 510641, China; 3.Guangzhou Institute of Chemistry, Chinese Academy of Sciences, Guangzhou 510650, China)

【机构】 中科院化学研究所华南农业大学中科院广州化学研究所中科院广州化学研究所 北京100080中科院广州化学研究所广东广州510650广东广州510641广东广州510650广东广州510650

【摘要】 以环氧树脂和丙烯酸为原料,合成了既可以光固化也可以热固化的丙烯酸环氧单酯,用FT-IR表征了合成产物以及光-热固化过程特征吸收峰的变化。研究了不同的稀释剂对光固化和光-热联合固化的凝胶率、吸水率、力学性能和热性能的影响,测试结果表明,光固化膜凝胶率低,柔韧性好,光-热固化以后断裂强度增大。

【Abstract】 A new typy of UV-curable and heat-curable epoxy acrylate was synthesized. The UV-curable formulations were prepared with different kinds of active diluents. The esterification and the cured films were discussed by means of FT-IR measurements. The gel content, water absorption and mechanical characterizations of the UV cured films and UV-heat cured films were investigated: the gel content, breaking strength and relative elongation of the UV-heat cured films is higher than that of the UV cured films.

【关键词】 紫外光固化热固化丙烯酸环氧树脂
【Key words】 UV-curableheat-curableacrylic acidepoxy
  • 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Engineering , 编辑部邮箱 ,2005年02期
  • 【分类号】O623
  • 【被引频次】33
  • 【下载频次】629
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