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一种新型金属配合物有机电致发光器件

Studies on a New Type of Metal Chelate OLED

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【作者】 郑加金华玉林吴晓明冯秀岚王树国孙媛媛徐风波张正之

【Author】 ZHENG Jia-jin~1, HUA Yu-lin~(1), WU Xiao-ming~(1,2), FENG Xiu-lan~1, WANG Shu-guo~1, SUN Yuan-yuan~1, XU Feng-bo~3, ZHANG Zheng-zhi~3 (1.Institute of Material Physics,Tianjin University of Technology,Tianjin 300191,China; 2.Institute of Modern Optics,Nankai University,Tianjin 300071,China; 3.Institute of Element,Nankai University,Tianjin 300071,China)

【机构】 天津理工学院材料物理研究所南开大学元素所南开大学元素所 天津300191天津300191天津300191南开大学现代光学所天津300071天津300071天津300071

【摘要】 以一种新型的含蒽荧光团双磷配体螯合Ag(L1Ag)为发光材料,制成有机电致发光二极管(OLEDs),结构分别为:ITO/L1Ag/Al;ITO/聚乙稀咔唑(PVK):L1Ag/Al。成功实现了明亮稳定的电致发光(EL),在534nm处均匀稳定地发出明亮的绿光。通过在L1Ag中混入空穴传输层材料聚乙烯咔唑(PVK),显著地提高了器件的综合发光性能,其光电流和量子效率分别提高了4.5倍和4.7倍,光电流达1.5×10-7A,量子效率为1.83×10-3%。对这种新型金属螯合物OLEDs的发光和电学性能进行了深入的研究。

【Abstract】 Two types of organic light-emitting devices(OLEDs) had been fabricated with a new OLEDs material L1Ag.The configuration of the devices were as follows:ITO/L1Ag/Al;ITO/PVK:L1Ag/Al.The bright and steady light emitting had been obtained,and the optical current and quantum efficiency of the later devices came to 1.5×10-7 A and 1.83×10-3%,which were 4.5 and 4.7 times higher than the former one,respectively. Details on the light-emitting characteristics of the devices were explained by the curves of current density-voltage,optical current-voltage and quantum efficiency-current density,which were measured using a quantum efficiency measure system including the keithley 485 picoammeter and 2 400 source meter.Last,we also discussed the emitting mechanisms of the new material and the devices.

【基金】 国家自然科学基金资助项目(60276027);天津市自然科学重点基金资助项目(023800511);天津市自然科学基金资助项目(033601211);天津市高校科技发展基金资助项目(9903114);天津市"材料物理与化学"重点学科资助项目
  • 【文献出处】 光电子·激光 ,Journal of Optoelectronics.laser , 编辑部邮箱 ,2005年01期
  • 【分类号】TN383.1
  • 【被引频次】3
  • 【下载频次】238
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