【摘要】 为了构造一个具有有效电荷转移的给-受体体系,通过1,3-偶极加成反应,由5-[2-′(4″-醛基苯氧丙氧苯基)]-10,15,20-三苯基卟啉(H2P-CHO)、肌氨酸和C60首次合成了一种新的以共价键相连的富勒烯-卟啉配体(H2P-C60),同时用该配体制备了其锌配合物(ZnP-C60),并用红外光谱、元素分析、电子光谱、核磁共振氢谱和质谱等方法进行了表征.更多还原

【Abstract】 In order to construct a donor-acceptor system with efficient electron transfer, a novel covalently linked fullerene-porphyrin ligand（H₂P-C_-{60-}） was synthesized by 1,3-dipolar cycloaddition reaction of C_-{60-}, sarcosine and H₂P-CHO, and it′s zinc derivative was prepared by metalation of H₂P-C_-{60-} and zinc acetate. The two new fullerene-porphyrin compounds were characterized by means of elemental analysis, IR, electronic spectra, ESI-MS and -{-}¹H NMR.They are also predicted to have good optical and electrical properties.更多还原