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聚氯乙烯/炭黑导电复合体系的压阻行为

Piezoresistance Behavior of Polyvinyl Chloride/Carbon Black Conductive Composites

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【作者】 徐文武宋义虎周剑锋郑强章明秋

【Author】 XU Wen-Wu~1, SONG Yi-Hu~1, ZHOU Jian-Feng~1, ZHENG Qiang~(1*), ZHANG Ming-Qiu~2(1. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China; 2. Materials Science Institude, Zhongshan University, Guangzhou 510275, China)

【机构】 浙江大学高分子科学与工程学系中山大学材料科学研究所 杭州310027杭州310027广州510275

【摘要】 研究了聚氯乙烯/炭黑(PVC/CB)导电复合体系在单轴压力作用下的压阻行为,发现CB含量对电阻-机械响应具有显著的影响.当CB含量低于渗流阈值时,PVC/CB复合材料呈现PPC效应;而高于渗流阈值时,呈现NPC效应.在渗流阈值附近,单轴压缩可诱导NPC效应的出现,或者抑制PPC效应.

【Abstract】 The piezoresistive behavior of polyvinyl chloride/carbon black(PVC/CB) conductive composites subjected to uniaxial compression-decompression cycles was studied. The composites exhibited a significant piezoresistance, when CB mass fraction w was located in the vicinity of the percolation threshold w__c. The composites displayed a positive pressure coefficient(PPC) effect at w<w__c and negative pressure coefficient(NPC) effect at w>w__c. Uniaxial compression might facilitate the NPC effect or weaken the PPC effect when w was located in the vicinity of w__c.

【基金】 国家杰出青年科学基金(批准号:50125312);国家自然科学基金重点项目(批准号:50133020)资助.
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2005年06期
  • 【分类号】TB332
  • 【被引频次】15
  • 【下载频次】247
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