节点文献
聚氯乙烯/炭黑导电复合体系的压阻行为
Piezoresistance Behavior of Polyvinyl Chloride/Carbon Black Conductive Composites
【摘要】 研究了聚氯乙烯/炭黑(PVC/CB)导电复合体系在单轴压力作用下的压阻行为,发现CB含量对电阻-机械响应具有显著的影响.当CB含量低于渗流阈值时,PVC/CB复合材料呈现PPC效应;而高于渗流阈值时,呈现NPC效应.在渗流阈值附近,单轴压缩可诱导NPC效应的出现,或者抑制PPC效应.
【Abstract】 The piezoresistive behavior of polyvinyl chloride/carbon black(PVC/CB) conductive composites subjected to uniaxial compression-decompression cycles was studied. The composites exhibited a significant piezoresistance, when CB mass fraction w was located in the vicinity of the percolation threshold w__c. The composites displayed a positive pressure coefficient(PPC) effect at w<w__c and negative pressure coefficient(NPC) effect at w>w__c. Uniaxial compression might facilitate the NPC effect or weaken the PPC effect when w was located in the vicinity of w__c.
【关键词】 聚氯乙烯;
炭黑;
压阻行为;
单轴压缩-解压缩;
唯象模型;
【Key words】 Poly(vinyl chloride); Carbon black; Piezoresistance behavior; Uniaxial compression-decompression; Phenomenological model;
【Key words】 Poly(vinyl chloride); Carbon black; Piezoresistance behavior; Uniaxial compression-decompression; Phenomenological model;
【基金】 国家杰出青年科学基金(批准号:50125312);国家自然科学基金重点项目(批准号:50133020)资助.
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2005年06期
- 【分类号】TB332
- 【被引频次】15
- 【下载频次】247