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Ag/TCNQ双层膜传质规律与模型的理论研究

Theoretical Studies on Transport Behavior and Model of Ag/TCNQ Double-layer Thin Film

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【作者】 谢亨博蒋益明郭峰刘平李劲

【Author】 XIE Heng-Bo, JIANG Yi-Ming, GUO Feng, LIU Ping, Li Jin~*(Department of Material Science, Fudan University, Shanghai 200433, China)

【机构】 复旦大学材料系复旦大学材料系 上海200433上海200433上海200433

【Abstract】 Ag/TCNQ double-layer films with different thicknesses were prepared on glasses substrate by alternately vacuum deposition of Ag and TCNQ. The metal-organic complex Ag-TCNQ formed through transport at room temperature and in atmosphere environment. The transport behavior in the film was studied by using transmission spectrum to monitor the process. An abnormal accelerated transport phenomenon was observed with the decrease of the thickness of the film, which was different from the parabola law between transport distance and transport time when the film was thicker. Tunneling and non-tunneling models were established respectively based on whether the tunneling condition was met. The theoretical analyses were carried out in detail.

【关键词】 薄膜传质隧穿
【Key words】 Thin filmTransportTunneling
【基金】 国家自然科学基金(批准号:10374015);国家“九七三”计划项目(批准号:2002CB613504);上海市科委纳米专项基金(批准号:0259nm089)资助.
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2005年06期
  • 【分类号】TB43
  • 【被引频次】1
  • 【下载频次】77
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