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相转移催化合成酯基取代酞菁铜及其光导性能
Synthesis of Ester Substituted Copper Phthalocyanines by Phase Transfer Catalysis Reaction and Their Photoconductivity
【Abstract】 Copper-tetra-4-(butyloxycarbonyl) phthalocyanine, copper-tetra-4-(octyloxycarbonyl) phthalocyanine and copper-tetra-4-(dodecoxycarboxyl) phthalocyanine were synthesized by the phase transfer catalysis reaction. The reaction has several advantages in comparison with the previous carboxyl-esterified method, such as the milder conditions, the shorter reaction time(3—6 h), the higher yield(>95%), and so on. Because of the difference in the substituent group length of these compounds, the morphology and the congregation of the molecules in their casting films is different, leading to the different photoconductivities of them.
【关键词】 酯基取代酞菁铜;
相转移催化反应;
光导性能;
【Key words】 Ester substituted copper phthalocyanines; Phase transfer catalysis reaction; Photoconductivity;
【Key words】 Ester substituted copper phthalocyanines; Phase transfer catalysis reaction; Photoconductivity;
【基金】 国家自然科学基金 (批准号 :90 2 0 10 0 9,5 0 2 2 5 3 12,5 0 43 3 0 2 0 )资助
- 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2005年01期
- 【分类号】O627
- 【被引频次】11
- 【下载频次】174