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氧化剂对甲壳素热降解性能的影响
Effect of oxidative additives on thermal degradation of chitin
【摘要】 讨论了硝酸铵、硫酸铵和浓硫酸对自制甲壳素热降解和热氧化降解过程的影响。硝酸铵加速甲壳素热降解和热氧化降解过程,而硫酸铵和浓硫酸加速甲壳素热氧化降解但推迟热降解过程。3种添加剂均改变了甲壳素等温热处理后凝聚相产物。
【Abstract】 Thermal and thermo-oxidative degradation of chitin with ammonium nitrate,ammonium sulfate and concentrated sulfuric acid were studied.Ammonium nitrate accelerated both thermal degradation and thermo-oxidative degradation,and ammonium sulfate and concentrated sulfuric acid promoted the thermo-oxidative degradation,but delayed thermal degradation.All of these three additives changed the condensed phase products of chitin after isothermal treatment.
【关键词】 甲壳素;
热降解;
热氧化降解;
氧化剂;
【Key words】 chitin; thermal degradation; thermo-oxidative degradation; oxidizing agent;
【Key words】 chitin; thermal degradation; thermo-oxidative degradation; oxidizing agent;
【基金】 教育部留学回国人员启动基金资助项目(K5115108)
- 【文献出处】 纺织学报 ,Journal of Textile Research , 编辑部邮箱 ,2005年06期
- 【分类号】O636.1;
- 【被引频次】2
- 【下载频次】152