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鲁米诺在氧化铟锡玻璃上的电聚合及电化学发光性能研究

The Studies of Electrochemical Polymerization of Luminol and the Electrochem ilum inescence Properties on Indium-tin Oxide Glass Electrode

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【作者】 王智泳郭文英狄俊伟屠一锋

【Author】 Wang Zhiyong, Guo Wenying, Di Junwei, Tu Yifeng* (College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006)

【机构】 苏州大学化学化工学院苏州大学化学化工学院 苏州215006苏州215006苏州215006

【摘要】 研究了鲁米诺在氧化铟锡(Indiumtinoxide,ITO)玻璃上的电聚合。通过循环伏安和紫外吸收光谱表征,在酸性条件下可以实现鲁米诺对ITO电极的电聚合修饰,聚合在ITO玻璃表面的鲁米诺保持其良好的电化学发光性能,考察了此修饰电极的性能以及相关因素对聚合膜的电化学发光强度的影响。

【Abstract】 The indium-tin oxide (ITO) glass was applied as the electrode to study the electrochemical polymerization and electrochemiluminescent (ECL) behavior of luminol on its surface. The experimental results indicated that the luminol could be polymerized on the surface of ITO glass in acidic solution. The cyclic voltammetry and ultraviolet-visible spectrometry were applied to confirm the polymerization of luminol and the ECL property of polymerized luminol on ITO was sell kept. Some other important factors had been also investigated.

【基金】 国家自然科学基金资助项目(No.20275025)
  • 【文献出处】 分析化学 ,Chinese Journal of Analytical Chemistry , 编辑部邮箱 ,2005年06期
  • 【分类号】O646
  • 【被引频次】21
  • 【下载频次】453
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