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一元卤代链烷常压沸点温度的三参数预报函数
Predicted function with three parameters of the boiling point temperature of homologous single haloid chain alkyl
【摘要】 依据由HM O理论导出的温度预报函数,从一元氟、氯、溴代直链烷同系物不确定度各异的40组常压沸点温度文献值中甄选出35组一致性样本,据此拟合出沸点温度预报函数中的三参数值,得到最大预报偏差分别为0.53 K,0.30 K,0.63 K,平均绝对误差分别为0.31 K,0.18 K,0.30 K。
【Abstract】 In this paper,based on the temperature predicted function deduced by HMO theory,the consistency specimens were selected from 40-group expanded uncertainty boiling point temperature literatures of homologous compounds about chain alkyl single fluorin,chlorine,bromine haloid.By choosing three parameters in the boiling point temperature predicted function,we obtained the maximum predicted error: 0.53 K,0.30 K,0.63 K and the maximum average absolute error: 0.31 K,0.18 K,0.30 K.
【关键词】 沸点;
一致性样本;
结构与性质;
一元卤代烷;
【Key words】 boiling point tempuerature; consistency specimens; structure and property; chain alkyl single haloid;
【Key words】 boiling point tempuerature; consistency specimens; structure and property; chain alkyl single haloid;
- 【文献出处】 佛山科学技术学院学报(自然科学版) ,Journal of Foshan University(Natural Science Edition) , 编辑部邮箱 ,2005年03期
- 【分类号】O623.21;
- 【下载频次】16