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多孔圆筒铸铁阳极电解制备高铁酸盐及处理联苯胺模拟废水的研究

Studies of Electro-Generated Ferrate at Porous Cylinder Castiron Anode and Degradated of Bennzidine Wastewater

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【作者】 方熠郑曦陈日耀陈震

【Author】 FANG Yi,ZHENG Xi,CHEN Ri-yao,CHEN Zhen(College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007,China)

【机构】 福建师范大学化学与材料学院福建师范大学化学与材料学院 福建福州350007福建福州350007福建福州350007

【摘要】 采用双阴极室隔膜电解槽,以多孔圆筒铸铁为阳极电解法制备水处理剂高铁酸盐.实验表明,在14 mol/L的NaOH溶液中,30℃下以30 mA/cm2的电流密度电解5.5 h可以获得36.8%的电流效率,高铁浓度可达到0.07 mol/L.用电解新制的高铁酸盐降解联苯胺模拟废水的结果表明,CODCr的去除率达85%,联苯胺最终被矿化成小分子无机物.

【Abstract】 Electro-generated water treatment FeO42- in diaphram cell with double cathedic chamber and porous cylinder cast iron as the anode has been reported. The experiment result showed that the eletro-effient and the concentration of FeO42- were higher by using double cylinder castiron anode.An optium result was obtained at J=30 mA/cm-2,30℃,14 mol/L NaOH,0.07 mol/L FeO42- was producted and the current yield was 36.8% for 5.5 h electrolysis. The result of ferrate oxidative degradation of benzidine wastewater showed the removal rate of CODCrwas more than 85% and the final products were small molecule inorganic compounds.

【基金】 福建省自然科学基金资助项目(A9910009)
  • 【文献出处】 福建师范大学学报(自然科学版) ,Journal of Fujian Normal University(Natural Science) , 编辑部邮箱 ,2005年03期
  • 【分类号】X703.1
  • 【被引频次】5
  • 【下载频次】100
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