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聚β-羟基丁酸PHB/蒙脱土纳米复合材料的结构与力学性能

Structure and Properties of Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHB)/OMMT Nanocomposites

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【作者】 张水生刘爱珍

【Author】 ZHANG Shui-sheng~1,LIU Ai-zhen~2(1. Dezhou Economic School , Dezhou Shandong 253000 , China; 2. Department of Chemistry,Dezhou University, Dezhou Shandong 253023,China)

【机构】 德州经济学校德州学院化学系 山东德州253020山东德州253023

【摘要】 用溶液复合法成功地制备了插层型PHB/蒙脱土纳米复合材料.采用X射线衍射(XRD)和透射电子显微镜(TEM)研究了复合材料的结构,发现硅酸盐片层间距从1.8 nm升至2.4 nm左右.同时研究了复合材料的结晶,熔融,和力学性能,发现有机蒙脱土的加入,可以加快PHB的结晶速度,降低熔融温度,提高了材料的力学性能,有机蒙脱土含量在3%时,其综合性能最佳.

【Abstract】 Poly(3-hydroxybutyrate) (PHB)/OMMT nanocomposites were prepared by mixing of PHB and organically modified montmorillonite (OMMT) as a type of layered OMMTs with chloroform. OMMT was prepared by surface treatment of montmorillonite (MMT) with hexadecyl-trimethylamine bromide. XRD and TEM results indicated that the PHB chains intercalated OMMT layers and the intercalated nanocomposites were obtained. The thermal and dynamic viscoelastic properties of nanocomposites were investigated using a differential DSC, TGA and DMA. It is found that the OMMT in the nanocomposites accelerate the crystallization of PHB as the effect of nuclii and decrease its melting temperature. The glass transition temperatures of the PHB/OMMT are higher than that of the original PHB. Tensile properties measurements of PHB/OMMT hybrids indicate that the addition of 3wt% of OMMT increases the tensile strength of 35.6 MPa, which is 32% higher than that of the original PHB.

【关键词】 纳米复合材料有机蒙脱土聚β-羟基丁酸
【Key words】 NanocompositeMontmorillonitePHB
  • 【文献出处】 德州学院学报(自然科学版) ,Journal of Dezhou University , 编辑部邮箱 ,2005年04期
  • 【分类号】TB383
  • 【被引频次】4
  • 【下载频次】235
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