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应用碳同位素动力学方法探讨阿克1气藏天然气的来源
Origin of natural gas from Ake 1 gas pool using the method of carbon isotope kinetics
【摘要】 阿克1气藏是塔西南前陆区喀什凹陷油气勘探上获得重大突破的工业性气藏。采用金管封闭体系热模拟实验和GC-IRMS碳同位素测定,结合运用GOR-ISOTOPEKINETICS专用软件,推导出了塔西南前陆区烃源岩(煤和泥岩)热解生成甲烷的碳同位素动力学参数。该区侏罗系煤、侏罗系泥岩和二叠系泥岩的平均活化能分别为225.86kJ/mol、194.03kJ/mol和223.45kJ/mol,甲烷(12CH4)的指前因子各为1.00×1014s-1、1.00×1013s-1、1.00×1014s-1。在此基础上,利用碳同位素动力学计算结果,并结合地质背景,进一步探讨了阿克1气藏天然气的来源,为天然气定量评价提供了新思路。阿克1气藏天然气为烃源岩过成熟阶段的烃产物,属于混源气,主要捕获了Ro为2.0%~3.6%阶段的天然气;其气源区包括喀什凹陷中心和阿克1井推覆体下盘,主力气源岩是石炭系烃源岩。
【Abstract】 The Ake 1 gas pool is a commercial gas reservoir that has made gre at breakthrough for oil and gas exploration in the Kashi Sag of the southwestern f oreland region, Tarim Basin. By using the thermal simulation experiment of the c losed gold-tube system and the measurement of GC-IRMS carbon isotope, combined with the GOR-ISOTOPE KINETICS specific software, the carbon isotopic kinetic p arameters of methane generated from source rocks in the Southwestern Foreland Re gion, Tarim Basin are obtained. The average activation energies of Jurassic coal , Jurassic mudstone and Permian mudstone samples selected from the Southwestern Foreland Region of the Tarim Basin are 225.86 kJ/mol, 194.03 kJ/mol, and 223.45 kJ/mol, respectively. The prefactor of their methane (12CH4) are 1.00×1014 s-1 , 1.00×1013 s-1, and 1.00×1014 s-1. Based on the above researches, combined with the geological background, the origin of natural gas from the Ake 1 gas poo l is further discussed by using the results of carbon isotope kinetic calculatio n. This provided a new thought for quantitatively evaluating the origin of natur al gas. It is suggested that natural gas of the Ake 1 gas pool was the evolution product of over-matured source rocks, and belonged to the mixed gas, the matur ity (Ro) of which is 2.0%~3.6%. The gas source kitchen of the Ake 1 gas pool included the center of Kashi Sag and the drop plate of Well Ake 1, the main gas of which was derived from Carboniferous source rock.
【Key words】 origin of natural gas; carbon isotope kinetics; pyrolysis experimen t; source rock; gas source; foreland region; Tarim Basin;
- 【文献出处】 地球化学 ,Geochimica , 编辑部邮箱 ,2005年05期
- 【分类号】P593;P618.13;
- 【被引频次】17
- 【下载频次】453