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应用碳同位素动力学方法探讨阿克1气藏天然气的来源

Origin of natural gas from Ake 1 gas pool using the method of carbon isotope kinetics

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【作者】 李贤庆肖贤明唐永春肖中尧米敬奎田辉刘德汉申家贵刘金钟

【Author】 LI Xian-qing1,2, XIAO Xian-ming1, TANG Yong-chun3, XIAO Zhong-yao4, MI Jin g-kui1, TIAN Hui1, LIU De-han1, SHEN Jia-gui1, LIU Jin-zhong1 1. State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geoche mistry, Chinese Academy of Sciences, Guangzhou 510640, China; 2. Key Laboratory of Coal Resources, Ministry of Education, China University o f Mining &Technology, Beijing 100083, China; 3. The Center of Petroleum Energy and Environmental Research, California Insti tute of Technology, 21910 Currier Rd, CA61769, USA; 4. Institute of Exploration and Development, Tarim Oil Field Company, Petro-C hina, Kuerle 841000, China

【机构】 中国科学院广州地球化学研究所有机地球化学国家重点实验室,中国科学院广州地球化学研究所有机地球化学国家重点实验室,美国加利福尼亚理工学院石油能源与环境研究中心,中国石油塔里木油田分公司勘探开发研究院,中国科学院广州地球化学研究所有机地球化学国家重点实验室,中国科学院广州地球化学研究所有机地球化学国家重点实验室,中国科学院广州地球化学研究所有机地球化学国家重点实验室,中国科学院广州地球化学研究所有机地球化学国家重点实验室,中国科学院广州地球化学研究所有机地球化学国家重点实验室 广东广州510640中国矿业大学煤炭资源教育部重点实验室,北京100083,广东广州510640,21910Currier Rd,CA61769,新疆库尔勒841000,广东广州510640,广东广州510640,广东广州510640,广东广州510640,广东广州510640

【摘要】 阿克1气藏是塔西南前陆区喀什凹陷油气勘探上获得重大突破的工业性气藏。采用金管封闭体系热模拟实验和GC-IRMS碳同位素测定,结合运用GOR-ISOTOPEKINETICS专用软件,推导出了塔西南前陆区烃源岩(煤和泥岩)热解生成甲烷的碳同位素动力学参数。该区侏罗系煤、侏罗系泥岩和二叠系泥岩的平均活化能分别为225.86kJ/mol、194.03kJ/mol和223.45kJ/mol,甲烷(12CH4)的指前因子各为1.00×1014s-1、1.00×1013s-1、1.00×1014s-1。在此基础上,利用碳同位素动力学计算结果,并结合地质背景,进一步探讨了阿克1气藏天然气的来源,为天然气定量评价提供了新思路。阿克1气藏天然气为烃源岩过成熟阶段的烃产物,属于混源气,主要捕获了Ro为2.0%~3.6%阶段的天然气;其气源区包括喀什凹陷中心和阿克1井推覆体下盘,主力气源岩是石炭系烃源岩。

【Abstract】 The Ake 1 gas pool is a commercial gas reservoir that has made gre at breakthrough for oil and gas exploration in the Kashi Sag of the southwestern f oreland region, Tarim Basin. By using the thermal simulation experiment of the c losed gold-tube system and the measurement of GC-IRMS carbon isotope, combined with the GOR-ISOTOPE KINETICS specific software, the carbon isotopic kinetic p arameters of methane generated from source rocks in the Southwestern Foreland Re gion, Tarim Basin are obtained. The average activation energies of Jurassic coal , Jurassic mudstone and Permian mudstone samples selected from the Southwestern Foreland Region of the Tarim Basin are 225.86 kJ/mol, 194.03 kJ/mol, and 223.45 kJ/mol, respectively. The prefactor of their methane (12CH4) are 1.00×1014 s-1 , 1.00×1013 s-1, and 1.00×1014 s-1. Based on the above researches, combined with the geological background, the origin of natural gas from the Ake 1 gas poo l is further discussed by using the results of carbon isotope kinetic calculatio n. This provided a new thought for quantitatively evaluating the origin of natur al gas. It is suggested that natural gas of the Ake 1 gas pool was the evolution product of over-matured source rocks, and belonged to the mixed gas, the matur ity (Ro) of which is 2.0%~3.6%. The gas source kitchen of the Ake 1 gas pool included the center of Kashi Sag and the drop plate of Well Ake 1, the main gas of which was derived from Carboniferous source rock.

【基金】 国家“十五”重点科技攻关项目(2001BA605A02-03-01和2004BA616A02-01-01);中国博士后科学基金(2002031282);国家自然科学基金(40072043);有机地球化学国家重点实验室开放基金(OGL-200403)~~
  • 【分类号】P593;P618.13;
  • 【被引频次】17
  • 【下载频次】453
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