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热海水中热浸镀用锌及锌铝合金的电化学性能

Electrochemical Properties of Zn/Zn-Al Alloys as Hot-Dip Galvanized Coating Protecting Steel in Hot Seawater

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【作者】 李鑫杜鸿雁魏绪钧李焰

【Author】 LI Xin~1,DU Hong-yan~2,WEI Xu-jun~1,LI Yan~3(1.School of Materials & Metallurgy,Northeastern University,Shenyang 110004,China;2.College of Chemistry and Chemical Engineering,Chongqing University,Chongqing 400044,China;3.Institute of Oceanology,Chinese Academy of Science,Qingdao 266071,China.)

【机构】 东北大学材料与冶金学院重庆大学化学化工学院中国科学院海洋研究所 辽宁沈阳110004重庆400044辽宁沈阳110004山东青岛266071

【摘要】 为了定量比较不同热浸镀层用金属(或合金)在热海水中对钢铁基体的阴极保护作用,参照国标GB/T 17848-1999的要求对几种典型的热浸镀用锌及锌铝合金测试了50℃条件下的恒电流性能,计算了电流效率,观察了腐蚀产物脱落情况及腐蚀均匀性,并据此评价了它们的电化学保护性能.结果表明:Zn的电化学性能最好,Zn-55Al-1.6Si合金的电化学性能最差,Zn-5Al-0.1RE,Zn-5Al-0.5Mg,Zn-6Al-3Mg,Zn-11Al-0.2Si-3Mg,Zn-25Al-0.2Si-0.2Mg和Zn-25Al-0.2Si-0.2RE合金介于二者之间.

【Abstract】 To compare quantitatively the cathodic protection effects of Zn and several ZnAl alloys as hot-dip galvanized coating materials on steel in 50?℃ seawater,their electrochemical properties were tested with constant current,according to the(China) national standard GB/T 17848-1999.Their current efficiencies were then calculated with surfaces corrosive peeling and homogeneity observed.Thus,their effects of anti-corrosion protection were evaluated.The results showed that the electrochemical properties of such zinc-aluminum alloys as Zn-5Al-0.1RE,Zn-5Al-0.5Mg,Zn-6Al-3Mg,Zn-11Al-0.2Si-3Mg,Zn-25Al-0.2Si-0.2Mg and Zn-25Al-0.2Si-0.2RE are medium,while Zn is the best and Zn-55Al-1.6Si alloy the poorest one.

【基金】 国家自然科学基金资助项目(40306013);青岛市自然科学基金资助项目(04-2-JZ-113)
  • 【文献出处】 东北大学学报 ,JOURNAL OF NORTHEASTERN UNIVERSITY , 编辑部邮箱 ,2005年11期
  • 【分类号】TG174.44;
  • 【被引频次】10
  • 【下载频次】257
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