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空气电池正极催化材料Mn-Co-O的研究

Research on catalytic material Mn-Co-O for cathode of air battery

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【作者】 张辉; 梁广川; 蒋巍;

【Author】 ZHANG Hui, LIANG Guang-chuan, JIANG Wei(Institute of Power Source and Ecomaterials Science, Hebei University of Technology,Tianjin 300130,China)

【机构】 河北工业大学能源与环保材料研究所; 河北工业大学能源与环保材料研究所 天津 300130; 天津 300130; 天津 300130;

【摘要】 催化材料是空气电池性能提高的技术关键。采用热分解法制备了金属氧化物催化剂Mn Co O。通过极化曲线及空气电极性能曲线测试发现:用酸化后的Mn3CoO7为催化剂的空气电极极化程度最小,在200mA/cm2的电流密度下,极化电位仅为-0 1522V;以100mA/cm2恒流电解,电极寿命可达800h,说明酸化后的Mn3CoO7催化剂具有良好的综合电化学性能。

【Abstract】 <Abstrcat>Catalytic material was a technological key to enhance the performance of air battery. Mn-Co-O catalysts were prepared by thermal decomposition method. Through the tests of steady polarization curve and performance curve of air electrode, it was found that air electrode with Mn3CoO7 catalyst after acidification had minimum extent of polarization and polarization (potential) was only (-0.152 2 V) when the current density was 200 mA/cm2, the life of air electrode could reach to 800 h at the steady electrolyte current density of 100 mA/cm2, which demonstrated good comprehensive electrochemical performance of the Mn3CoO7 catalyst after acidification.

【关键词】 空气电极; 催化剂; 硝酸盐; 热分解;
【Key words】 air electrode; catalyst; nitrate; thermal decomposition;
【基金】 河北省科技攻关计划项目资助(01212102)
  • 【分类号】TM911
  • 【被引频次】2
  • 【下载频次】129
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