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用微波技术制备NiW /TiO2-Al2O3加氢脱硫催化剂

Preparation of NiW/TiO2-Al2O3 Hydrodesulfurization Catalyst with Microwave Technique

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【作者】 刘百军查显俊孟庆民侯辉娟高山松张金霞盛世善杨维慎

【Author】 LIU Baijun 1* , ZHA Xianjun 1, MENG Qingmin 1, HOU Huijuan 1, GAO Shansong 1, ZHANG Jinxia 1, SHENG Shishan 2, YANG Weishen 2(1 The Key Laboratory of Catalysis, China National Petroleum Corporation, University of Petroleum, Beijing 102249, China; 2 State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China)

【机构】 石油大学(北京)中国石油天然气集团公司催化重点实验室中国科学院大连化学物理研究所催化基础国家重点实验室中国科学院大连化学物理研究所催化基础国家重点实验室 北京102249北京102249辽宁大连116023辽宁大连116023

【摘要】 采用微波技术制备了NiW /TiO2 Al2 O3 加氢脱硫催化剂,并用NH3 TPD ,Py FT IR ,TPR和TPS(程序升温硫化)对催化剂进行了表征;以噻吩为模型化合物,在中压固定床微反装置上考察了催化剂的加氢脱硫性能.结果表明,在w(TiO2 ) =15 %的催化剂样品中,微波处理的催化剂的活性比常规催化剂高.微波处理改变了载体和催化剂表面的酸性质,催化剂样品表面的强酸酸量减少,弱酸和中强酸酸量增加.微波处理的催化剂的还原性能和硫化性能均好于常规法制备的催化剂.这可能是微波技术制备的催化剂具有较高加氢脱硫活性的原因.

【Abstract】 The NiW/TiO2-Al2O3 catalyst samples were prepared by conventional drying method (CON-Cat) and by microwave irradiation method (MW-Cat and MW-Cat1). The catalyst samples were characterized with NH3-temperature-programmed desorption, Py-FT-IR, temperature-programmed reduction, and temperature-programmed sulfurization techniques. The hydrodesulfurization (HDS) reactivity of thiophene over them was studied in a fixed-bed microreactor. The thiophene conversion over MW-Cat increased from 70.9% at 16 h to 71.8% at 19 h, while the thiophene conversion over MW-Cat1 kept to 71% after 17 h and then increased very slowly. The HDS reactivity over CON-Cat increased slowly after 15 h and the thiophene conversion increased from 63.3% at 15 h to 69.4% at 19 h. The activity difference between CON-Cat and MW-Cat was due to the different sulfidation performance. MW-Cat or MW-Cat1 could be sulfided to some extent by using shorter time than CON-Cat. The surface acidic properties of MW-Cat and MW-Cat1 were changed with microwave irradiation power and time. The amounts of weak and medium acid sites in MW-Cat and MW-Cat1 increased, while that of strong acid sites decreased. The strength order of weak and medium acids was MW-Cat<MW-Cat1<CON-Cat. MW-Cat and MW-Cat1 were favorable for their sulfurization and had higher activity than CON-Cat because more active species were formed in MW-Cat and MW-Cat1 with microwave irradiation. MW-Cat and MW-Cat1 were more favorable for their reduction than CON-Cat.

【基金】 国家重点基础研究发展规划项目 (973计划 ) (2 0 0 4CB2 1780 5 );中国科学院大连化学物理研究所催化基础国家重点实验室开放课题 (0 2 G0 14 )
  • 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2005年06期
  • 【分类号】TE624.55
  • 【被引频次】22
  • 【下载频次】500
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