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以石油醚为油相的微乳液的增溶水量研究

Study of water solubilization performance of microemulsions using petroleum ether as oil phase

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【作者】 万涛王跃川

【Author】 WAN Tao~(1,2),WANG Yue-chuan~1 (1.College of Polymer Science and Engineering,State Key Laboratory of Polymer Materials Engineering,Sichuan University,Chengdu 610065,China;2.College of Materials and Bioengineering,Chengdu University of Technology,Chengdu 610059,China)

【机构】 四川大学高分子材料与工程国家重点实验室高分子材料科学与工程学院四川四川大学高分子材料与工程国家重点实验室高分子材料科学与工程学院四川 成都610065 成都理工大学材料与生物工程学院四川成都610059成都610065

【摘要】 考察了助表面活性剂与表面活性剂的质量比(m2)、丙烯酸(AA)、丙烯酰胺(AM)、表面活性剂和氧化还原引发剂(NH4)2S2O8-NaHSO3等多种因素对CTAB(SDBS)/正戊醇/石油醚/水体系溶水量的影响,首次探明了以石油醚为油相的微乳液形成的较适宜条件,结果表明:对于CTAB微乳液体系,m2在0.6~2.5能形成微乳状液,而对于SDBS微乳液体系,m2仅在0.3~1.5能形成微乳状液;加入适量单体AA、AM和氧化还原引发剂(NH4)2S2O8-NaHSO3可以提高溶水量。

【Abstract】 Effects of the mass ratio of cosurfactant to surfactant(m2),as well as the amount of acrylic acid,acrylamide and redox initiator(NH42S2O8-NaHSO3 on the water solubilization performance of microemulsions CTAB(SDBS)/n-pentanol/petroleum ether/water system were examined.The suitable conditions for the formation of microemulsions based on petroleum ether as oil phase were found.Experimental results showed that the petroleum ether-based microemulsions can be formed with the value of m2 within 0.6~2.5 and 0.3~1.5,using CTAB and SDBS as the surfactant respectively.The water solubilization performance of the prepared microemulsions can be enhanced by adding a suitable amount of acrylic acid,acrylamide and redox initiator.

【关键词】 表面活性剂微乳液溶水量
【Key words】 surfactantmicroemulsionwater solubilization
  • 【文献出处】 日用化学工业 ,China Surfactant Detergent & Cosmetics , 编辑部邮箱 ,2005年05期
  • 【分类号】O648.2
  • 【被引频次】12
  • 【下载频次】209
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