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MC尼龙/CaCO3纳米复合材料的制备及力学性能研究

STUDY ON PREPARATION AND MECHANICAL PROPERTIES OF MC NYLON/CaCO3 NANO COMPOSITES

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【作者】 林轩张平民曾余平尹周澜陈启元

【Author】 Lin Xuan~1,3, Zhang Pingmin~1, Zeng Yuping~2, Yin Zhoulan~1, Chen Qiyuan~1 (1.College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;2.Nanfang Nylon Products Co. Ltd., Guangzhou 510700, China;3.Chemistry Department, Zhanjiang Normal College, Zhanjiang 524048, China)

【机构】 中南大学化学化工学院广州南方尼龙制品公司中南大学化学化工学院 长沙410083湛江师范学院化学系湛江524048长沙410083广州510700长沙410083

【摘要】 用超声分散原位聚合法制备了铸型(MC)尼龙/CaCO3纳米复合材料,用扫描电镜(SEM)对纳米CaCO3粒子在基体中的分散情况进行了表征,研究了纳米CaCO3用量对复合材料力学性能的影响。研究结果表明,纳米CaCO3对MC尼龙具有增韧和增强的双重效果,复合材料的拉伸强度和缺口冲击强度随着纳米CaCO3用量的增加先提高后降低,而断裂伸长率随着纳米CaCO3用量的增加而降低,当纳米CaCO3的用量为2%~3%时复合材料的综合性能最好。

【Abstract】 Monomer casting (MC) nylon/CaCO3 nano composites were prepared by ultrasonic dispersion in situ polymerization method. The dispersion of nano-CaCO3 in the matrix was observed by scanning electron microscopy (SEM) and the effects of nano-CaCO3 content on the mechanical properties of the composites were studied. Experimental results showed that nano-CaCO3 had double effects of toughening and reinforcing on MC nylon. The tensile strength and notch impact strength of the composites increased first and decreased afterwards as the increase of nano-CaCO3 content, but the elongation at break of the composites decreased as the increase of nano-CaCO3 content. When nano-CaCO3 content was 2.0%-3.0%, the mechanical properties of the composites were the best.

【基金】 广东省自然科学基金资助项目(011786)
  • 【文献出处】 工程塑料应用 ,Engineering Plastics Application , 编辑部邮箱 ,2005年07期
  • 【分类号】TQ323.6
  • 【被引频次】21
  • 【下载频次】284
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